The jahn teller effect

7: Jahn-Teller effect

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Jahn–Teller effect

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During the Manhattan Project, Edward Teller headed a group at Los Alamos in the Theoretical Physics division. Teller was a major proponent of the hydrogen bomb. This position pitted him against Oppenheimer, and divided the scientific community.

The effect of Jahn-Teller distortions is best documented for Cu(II) complexes (with 3 electrons in the e g level) where the result is that most complexes are found to have elongation along the z-axis.

The Jahn-Teller Theorem does NOT say how large a distortion should occur. Take for example, the 3 copper complexes shown below.

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Jahn-Teller Distortion in Cu(II) Complexes d x2-y2 e g energy d xy d z2 t 2g Cu(II) in regular octa-dxz d yz [C F ]4- hedral environment Cu(II) after J-T distortion [CuF. The Jahn-Teller Theorem (named after Hermann Arthur Jahn and Edward Teller), was published in and essentially means that: "any non-linear molecular system in a degenerate electronic state will be unstable and will undergo distortion to form a system of lower symmetry and lower energy thereby removing the degeneracy".

"The pseudo Jahn–Teller effect is the only source of instability and distortions of high-symmetry configurations of polyatomic systems in nondegenerate states, and it contributes significantly to the instability in degenerate states".

An informally written, engaging textbook, first of its kind,to offer a highly physical approach to inorganic chemistry Unlike other chemistry textbooks, whose memorization-heavyvolumes often dispirit student interest, this text is designed forupper-level undergraduates (who have already taken physicalchemistry) and introductory-level graduate students taking aninorganic or advanced inorganic.

The jahn teller effect
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Edward Teller | Biography |